Synthesis of p-Nitrophenyl 4-O-(alpha-D-Mannopyranosyl)-alpha-L-rhamnoside and p-Acetamidophenyl 4-O-(beta-D-Mannopyranosyl)-alpha-L-rhamnoside.
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منابع مشابه
Methyl 3-O-α-d-mannopyranosyl β-d-glucopyranoside tetrahydrate
The title compound, C(13)H(24)O(11)·4H(2)O, forms extended hydrogen-bonded networks. These are present between disaccharides, but not as inter-residue hydrogen bonds, as well as to water mol-ecules that in addition form an inter-molecular chain of hydrogen bonds. The conformation of the disaccharide is described by the glycosidic torsion angles ϕ(H) = -34° and ψ(H) = -5°. Macroscopically, the d...
متن کاملThe cardioprotective effects of 4-O-(2″-O-acetyl-6″-O- p-coumaroyl-β-D-glucopyranosyl)-p-coumaric acid (4-ACGC) on chronic heart failure
The 4-ACGC isolated from BP was prepared to investigate the cardioprotective effects on attenuating chronic heart failure in vivo and in vitro. A chronic heart failure (CHF) rat model was established to investigate the cardioprotective effects of 4-ACGC. From this, several cardiac function indexes were recorded. The inflammatory markers including tumor necrosis factor-α (TNF-α), Interleukin-6 (...
متن کاملThe cardioprotective effects of 4-O-(2″-O-acetyl-6″-O- p-coumaroyl-β-D-glucopyranosyl)-p-coumaric acid (4-ACGC) on chronic heart failure
The 4-ACGC isolated from BP was prepared to investigate the cardioprotective effects on attenuating chronic heart failure in vivo and in vitro. A chronic heart failure (CHF) rat model was established to investigate the cardioprotective effects of 4-ACGC. From this, several cardiac function indexes were recorded. The inflammatory markers including tumor necrosis factor-α (TNF-α), Interleukin-6 (...
متن کاملSynthesis of the pentasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 4 in the form of its methyl ester 2-(trimethylsilyl)ethyl glycoside.
Starting from D-mannose, D-glucose and L-fucose, the pentasaccharide derivative methyl 2,3,4-tri-O-benzyl-alpha-L-fucopyranosyl-(1-->3)-2-O-acetyl-4,6-O-benzylidene-alpha-D-mannopyranosyl-(1-->3)-2-O-acetyl-6-O-benzyl-4-O-(2,3,4-tri-O-benzyl-alpha-L-fucopyranosyl)-alpha-D-mannopyranosyl-(1-->4)-[2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-beta-D-glucopyranosid]uronate was synthesized. This compound...
متن کاملBiphasic Association of p-Nitrophenyl 2-O-cx-D-Mannopyranosyl-cx-D- mannopyranoside and Concanavalin A as Detected by Stopped Flow Spectroscopy*
Kinetics of binding of p-nitrophenyl 2-O-a-n-mannopyranosyl-a-n-mannopyranoside (Mz) to concanavalin A (con A) were examined. The time course of formation of a Mz*con A complex is clearly biphasic, whereas the association with con A of p-nitrophenyl 2-O-methyl-an-mannopyranoside and other monosaccharides is a monophasic process. The biphasic time course of the binding of Mz to con A is most sim...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1975
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.29b-1031